I would check your water pump for leaking out of the little hole in the bottom.
I believe the overflow reserve is generally for expansion of the coolant and will return back into the radiator once the engine starts to cool, so it should keep a reasonably constant level.
If the radiator has lost coolant due to a leak more will flow from the bottle causing it to become empty over time (depending on the amount being lost)
I also found my bottle was filling up a bit more than usual when hot, so I replaced the radiator cap and solved my overheating problems. The old cap had lost it's spring pressure and was releasing the coolant into the overflow when it tried to pressurise, this was causing less coolant to be held in the radiator causing pinging and the engine slowly overheating after about 3/4 hr travelling on a hot day. (all good now, $19 from the dealership) You can tell if this is happening by the top radiator hose not having any pressure in it.
hope all this bullshite helps.
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Jake
1996 xj sport
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