I tend to put a thin smear of RTV or other 'gasketmaker' on both sides of my gaskets, to seal of little burs or imperfections. But that's my personal modus operandi.
Regarding the torque specs, good question, I dont know if your new stainless steel would have significantly different specs regarding that, but sure others who done this chime in on this.
btw, been looking at the headers on ebay, were yours the $300+ ones?
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97 XJ 4.0 Sport (Nov)
Chrysler 8.25"
189.000 km
Stop calling your car a "she". It's a car.
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